First read the instructions.
https://www.glow-worm.co.uk/glow-worm/f ... 157170.pdf I note on page 24 it gives the connections, I can see an ebus connection but nothing about using it with a thermostat, so it would seem this boiler uses a mark/space ratio (it turns it off/on) so it would seem easy to add, or move the controls.
However much depends on what cables are already installed, and how the boiler needs controlling? In the main we use a series of plans, with a combi very easy. But where it heats the domestic hot water (DHW) we have a number of options.
1) Thermo syphon
2) Pumped
3) Time only control
4) Thermostatic control
5) 2 port valves
6) 3 port valves
Since you say airing cupboard I would assume it does DHW as well as central heating, the normal method is to use wiring centres to reduce the number of wires between the cylinder thermostat, motorised valves, room thermostats and pumps.
When I came to alter the controls on my central heating it was the cables or more lack of them, which forced me to adopt a way of controlling it. Some times wireless can be used, however consider if they fail safe, if when batteries go flat or some thing blocks signal it can continue heating 24/7 that is not good, some wall thermostats look for signal every 1/2 hour and if no signal shut down (fail safe) others don't.
So basic method is, a thermostat is powered from a programmer, then thermostats often one wall and one tank then power the motorised valves, the valves then power the boiler and if required pump.
Central heating nearly always has a pump, but DHW can be thermo-syphon.[attachment=0]C_Plan_My_HouseC.jpg[/attachment] This is the plan for my house, the two wiring centres the boiler, pumps, valves in fact all but the wall thermostat was in the flat below the main house, only 2 wires link main house and flat below, so selected Nest as it allowed me full control from main house with only 2 wires.
That is what you need to work out, how many wires do you need, how many have you got, and if not enough how easy is it to add extras.